Product ID:PENAIR HD-1,MIL-C-87937B,TYPE 1
MSDS Date:03/16/1995
FSC:6850
NIIN:01-390-7811
MSDS Number: BVFPV

Emergency Phone: 201-569-5340

Info Phone: 201-567-3000

Preparer: C. GOOD

Cage: 56883

Telephone: 201-567-3000

Cage: 56883

D-LIMONENE

CAS: 5989-27-5

RTECS: GW6360000

LD50 LC50 Mixture:ORAL LD50 (RAT) IS UNKNOWN.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYE-MAY CAUSE IRRITATION ON PROLONGED
CONTACT. HIGH VAPOR CONCENTRATIONS MAY BE IRRITATING.
SKIN-FREQUENT/PROLONGED CONTACT MAY IRRITATE/DRY SKIN, OR CAUSE
DERMATITIS. INHALATION-HIGH VAPOR/AEROSOL CO NCENTRATIONS ARE
IRRITATING TO RESPIRATORY TRACT & MAY CAUSE CNS EFFECTS.
INGESTION-SMALL AMOUNTS OF THIS LIQUID MAY BE DRAWN INTO THE LUNGS
BY EITHER SWALLOWING OR VOMITING. THIS MAY CAUSE SEVERE & D ELAYED
HEALTH EFFECTS SUCH AS INFLAMMATION OF THE LUNGS & INFECTION OF THE
BRONCHI. INGESTION MAY CAUSE IRRITATION OF DIGESTIVE TRACT.
CHRONIC:INFLAMMATION OF MUCOUS MEMBRAMES & RESPIRATORY TRACT MAY
OCCUR UPON PROLONGED BREATHING OF MIST.
Explanation of Carcinogenicity:PENAIR HD-1 DOES NOT CONTAIN ANY
COMPONENT LISTED AS A CARCINOGEN BY IARC, NTP OR OSHA.

First Aid:EYE: FLUSH EYES WITH LARGE AMOUNT OF WATER. SEE PHYSICIAN
IMMEDIATELY. SKIN: FLUSH SKIN WITH LARGE AMOUNT OF WATER. REMOVE
CONTAMINATED CLOTHING AND LAUNDER BEFORE REUSE. IF SKIN IRRITATION
DEVELOPS O R PERSISTS, CONSULT PHYSICIAN. INHALATION: REMOVE PERSON
TO FRESH AIR. ADMINISTER OXYGEN OR ARTIFICIAL RESPIRATION AS
NEEDED. CALL A PHYSICIAN IMMEDIATELY. INGESTION: IF SWALLOWED, GIVE
PLENTY OF MILK OR WATER. DO NOT INDUCE VOMITING. USE A STOMACH
PUMP. CALL A PHYSICIAN IMMEDIATELY.

Flash Point Method:PMCC
Flash Point:=52.C, 125.6F
Autoignition Temp:Autoignition Temp Text:NOT DE
Lower Limits:NOT DETERMIN
Upper Limits:NOT DETERMIN
Fire Fighting Procedures:EITHER ALLOW FIRE TO BURN OUT UNDER CONTROLLED
CONDITIONS OR EXTINGUISH WITH WATER, FOAM OR DRY CHEMICAL. COOL
EXPOSED CONTAINERS WITH WATER SPRAY.
Unusual Fire/Explosion Hazard:COMBUSTIBLE LIQUID. CAN FORM FLAMMABLE
MIXTURES AT OR ABOVE THE FLASH POINT. CONTAINERS CAN RUPTURE AND
EXPLODE UNDER FIRE CONDITIONS DUE TO PRESSURE AND VAPOR BUILDUP.

Spill Release Procedures:LAND SPILL: ELIMINATE SOURCES OF IGNITION. FOR
SMALL SPILL, USE ABSORBENT MATERIAL SUCH AS TOWELS OR ABSORBENT
POWDERS. PUT ALL MATERIAL INTO PROPER WASTE DISPOSAL CONTAINER WITH
LID TIGHTLY COVERED. FOR LARGER SPILLS, CONTAIN SPILL, RECOVER
FREE LIQUID & USE ABSORBENT MATERIAL TO DRY AREA. PUT ALL MATERIAL
INTO APPROPRIATE WASTE CONTAINERS.

Handling and Storage Precautions:STORAGE TEMPERATURE, F: AMBIENT. DO
NOT STORE AT TEMPERATURES CONSISTENTLY ABOVE 120F, OR BELOW 32F TO
ENSURE PRODUCT INTEGRITY. IF PRODUCT FREEZES, THAW & MIX BEFORE
USING. GENERAL: KEEP AWAY FROM AR TIFICIAL HEAT SOURCES, OPEN
FLAMES, & OTHER IGNITION SOURCES. DO NOT STORE NEAR STRONG
OXIDANTS. .
Other Precautions:WATER SPILL-REMOVE PRODUCT FROM WATER SURFACE BY
SKIMMING OR WITH SUITABLE ABSORBENTS. THIS PRODUCT CONTAINS
SURFACTANTS WHICH WILL CAUSE IT TO DISPERSE IN WATER. LOCALIZED
HIGH CONCENTRATIONS OF THIS PRODUCT MAY CAUSE FISH KILLS, BUT NO
PERSISTENT OR LONG TERM EFFECTS WILL RESULT. CHECK WITH LOCAL
AGENCIES.

Respiratory Protection:NONE NORMALLY REQUIRED. IF PEL/TLV EXCEEDED, A
NIOSH/MSHA APPROVED ORGANIC VAPOR MASK SHOULD BE USED.
Ventilation:NONE NEEDED UNDER NORMAL USE CONDITIONS. ADEQUATE
VENTILATION MUST BE PROVIDED IN CONFINED AREAS.
Protective Gloves:SOLVENT RESISTANT GLOVES SHOULD BE USED.
Eye Protection:SAFETY GLASSES RECOMMENDED FOR WORKPLACE CONDITIONS
Other Protective Equipment:DEPENDING ON HOW THE PRODUCT IS USED, OTHER
PROTECTIVE GEAR, INCLUDING SPLASHPROOF GOGGLES OR FACE SHIELD,
RUBBER BOOTS, APRON, GAUNTLETS, OR RAINGEAR SHOULD BE WORN.
Supplemental Safety and Health
VENTILATION: FOR ENCLOSED WORK SPACES, OR WHERE LARGE AMOUNTS OF THE
PRODUCT ARE BEING USED, THE USE OF FANS OR OTHER MECHANICAL
VENTILATION IS RECOMMENDED. IF VENTILATION IS INADEQUATE, AN
ORGANIC VA POR MASK SHOULD BE USED. AVOID BREATHING OF VAPORS &
SPRAY MIST. USE COARSE SPRAY ONLY. DO NOT FOG THIS PRODUCT.

HCC:F4
Boiling Pt:=100.C, 212.F
Decomp Temp:=204.C, 399.2F
Vapor Pres:EQUAL TO WATER
Vapor Density:+WATER
Volatile Org Content %:50
Spec Gravity:0.95
pH:9.0
Evaporation Rate & Reference:EQUAL TO WATER.
Solubility in Water:EMULSIFIES
Appearance and Odor:CLEAR AMBER LIQUID. CITRUS ODOR.

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:THIS PRODUCT IS STABLE AND HAZARDOUS
POLYMERIZATION WILL NOT OCCUR.
Hazardous Decomposition Products:SMOKE, FUMES, AND OXIDES OF CARBON.
Conditions to Avoid Polymerization:WILL NOT OCCUR.

Waste Disposal Methods:RCRA HAZARD CLASS: D001 IGNITABLE HAZARDOUS
WASTE.

Toxicological Information:CHRONIC: INGESTION OF LARGE AMOUNTS OF
DIMONENE HAS CAUSED KIDNEY & LIVER DAMAGE IN MALE RATS BUT NOT IN
FEMALE RATS OR MICE OF BOTH SPECIES.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Transport Information:DEPARTMENT OF TRANSPORTATION (DOT): PROPER
SHIPPING NAME: COMBUSTIBLE LIQUID, N.O.S. (CONTAINS D-LIMONENE),
HAZARD CLASS: COMBUSTIBLE LIQUID. IDENTIFICATION NUMBER: NA1993,
PACKING GROUP: III. LABEL: NOT REQUIRED FOR NONBULK. INTERNATIONAL
REGULATIONS: PROPER SHIPPING NAME: FLAMMABLE LIQUID, N.O.S.
(CONTAINS D-LIMONENE). HAZARD CLASS: 3, IDENTIFICATION NUMBER:
UN1993, PACKING GROUP: III. LABEL: FLAMMABLE. NOTE: INTERNATIONAL
REGULATIONS MUST BE USED FOR ALL AIR & SEA-GOING VESSEL SHIPMENTS.
FLASH POINT: 125F TCC, PH=9.0.

SARA Title III Information:311/312 HAZARD CATEGORIES: ACUTE HEALTH,
CHRONIC HEALTH, FIRE. 313 REPORTABLE INGREDIENTS: DIETHYLENE GLYCOL
MONOBUTYL ETHER CAS# 112-34-5, 10-15%.
Federal Regulatory Information:CERCLA: THIS PRODUCT DOES NOT CONTAIN
ANY CERCLA REPORTABLE MATERIALS. CHECK WITH LOCAL AND STATE
AUTHORITIES TO DETERMINE IF OTHER REPORTING REQUIREMENTS ARE
APPLICABLE. RCRA HAZARD CLASS: D001 IGNI TABLE HAZARDOUS WASTE.
TSCA: THE INGREDIENTS IN THIS PRODUCT ARE LISTED ON THE TSCA
INVENTORY.
State Regulatory Information:NEW JERSEY RIGHT-TO-KNOW INFORMATION: THIS
PRODUCT CONTAINS WATER (CAS#7732-18-5), D-LIMONENE (CAS#
5989-27-5), POTASSIUM FATTY ACID SOAP (CAS# 61790-44-1), DIETHYLENE
GLYCOL MONOBUTYL ETHER (CAS#112- 34-5), AND NONYLPHENOL ETHOXYLATE
(CAS#9016-45-9). CALIFORNIA PROPOSITION 65 INFORMATION: THIS
RPODUCT DOES NOT CONTAIN ANY CHEMICALS RECOGNIZED BY THE STATE OF
CALIFORNIA TO CAUSE CANCER AND/OR BIRTH DEFECTS OR REPRODUCTIVE
HARM.